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The trouble usually starts when one or more of those variables gets pushed too far

Thus, glutathione is an essential part of the way cells balance ROS on a constant basis, as well as being available in situations where oxidative stress is generated by toxins, disease, or other pathological conditions.[ref] Glutathione peroxidase (GPX1, GPX2,3,4) antioxidant in cells Glutathione S-transferases (GSTs) are a family of enzymes that bind glutathione to toxic substances to remove them from the cell and then out of the body

Etzioni, A

Instead GHK seems to have a more multi-faceted effect on many different systems

Wounds and wound healing

The compound's stability in properly formulated products, combined with its gentle nature and low irritation potential, makes it ideal for both leave-on and rinse-off applications